Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates (IMAGE)

Yokohama National University

Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates

Caption

This illustration visualizes a novel electrochemical transformation in which a single carbon atom—derived from a diazo compound—is selectively inserted into the pyrrole ring via a distonic radical cation intermediate. The origami-like transformation of molecular building blocks symbolizes the precise and programmable synthesis of substituted pyridines. The reaction proceeds under electrochemical conditions without the need for external reagents, showcasing a new strategy for constructing complex aromatic molecules.

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YOKOHAMA National University

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