Crystal structure of new pigments (IMAGE)
Caption
Schematic representation of thortveitite-like structure of Zn2-xNixV2O7 (top). Substitution of Ni for Zn produces yellow, orange and reddish hues as x value is varied (bottom). Zinc/Nickel atoms are shown as red spheres located in a distorted five-coordinated trigonal bipyramidal environment formed by oxygen atoms (turquoise spheres). Vanadium atoms are shown as yellow spheres located in a tetrahedral arrangement formed by oxygen atoms. Image provided by Mas Subramanian, OSU College of Science.
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Image provided by Mas Subramanian, OSU
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