Cobalt‑Based Electrocatalysts for Sustainable Nitrate Conversion: Structural Design and Mechanistic Advancements (IMAGE)
Caption
- This review covers almost all cobalt-based electrocatalysts for nitrate reduction reaction (NO3RR), including metallic cobalt, cobalt alloys, cobalt compounds, cobalt single-atom and molecular catalysts, etc.
- The mechanism of enhancing the NO3RR performance by suppressing the hydrogen evolution reaction, as well as the durability and degradation processes, was discussed from the perspective of the electronic structure and adsorption behavior.
- The influence of different coordination environments of Co active sites on NO3RR performance was discussed, including different isomorphic forms of the same elements around Co, different types of elements, doping of trace elements, and in situ evolution of constituent elements, etc.
Credit
GuoLiang Chang, Xueqiu Chen, Jing-Jing Lv, Zhijie Kong*, Zheng-Jun Wang*.
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CC BY-NC-ND