Schematic illustration of LiPSs conversion on Co9S8-Mn3O4@CNF. (IMAGE)
Caption
Based on the HSAB theory, when the pristine Mn3O4 adsorbs LiPSs, the O atoms preferentially adsorb Li atoms in LPSs through the “hard to hard” interactions. In contrast, the Mn atoms in the softened Mn3O4 via Co9S8 electron injection adsorb the S atoms in LiPSs by “soft to soft” orbital interactions.
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Nano Research, Tsinghua University Press
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