Figure Abstract (IMAGE)
Caption
A water-involved electrochemical transfer hydrogenation and dehydrogenation of N-heterocycles is developed. Self-supported MoNi4 alloy is designedly synthesized as the bifunctional electrode enabling both the transfer hydrogenation of unsaturated N-heterocycles using the active hydrogen atom (H*) in situ produced by water electrolysis, and the oxidative dehydrogenation of saturated N-heterocycles using the in situ formed NiIII species.
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Chinese Journal of Catalysis
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