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The rational design of catalysts needs to be based on theoretical guidance. We summarize the development and content of classical theories in the field of electrocatalysis. Including Sabiter principle, Volcano curve, Brønsted-Evans-Polanyi relationship, Scaling relationship and descriptors commonly used in a serious of electrochemical reactions (HER, OER, ORR, NRR and CO2RR).
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Chinese Journal of Catalysis
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