Reliable temperature sensing above 1000 °C remains difficult because conventional thermistor ceramics often suffer from nonlinear response and resistance drift during prolonged thermal exposure. Researchers developed Mo-regulated high-entropy niobate ceramics to coordinate local lattice distortion, carrier transport, and grain–grain-boundary energy barriers. The optimized ceramic delivered highly linear sensing from −50 to 1250 °C (R2 = 0.99907), a B-value fluctuation of only 4.44%, and a stabilized-stage resistance drift of 1.09% after 1000 h at 1250 °C, showing the potential for hypersonic vehicles, aero-engines, and other extreme-temperature systems.