Low-speed magnetic stirring activation of peroxymonosulfate with TiO2 nanoparticles as tribocatalyst for degradation of organic pollutants
Peer-Reviewed Publication
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Sulfate radical (SO4•- )-based advanced oxidation processes (AOPs) are appealing for removing persistent organic pollutants from wastewater, but current mainstream activation of peroxydisulfate (PDS) and peroxymonosulfate (PMS) through heating, light irradiation, electricity or ultrasound is too energy-intensive to large-scale wastewater treatment. On the other hand, low-frequency mechanical energy, which is not only abundant in ambient environment but also easy to scale up, has been rarely explored in sulfate radical (SO4•- )-based AOPs for decades.
A new study uses theoretical modelling to reveal the key role of graphene in TiO2/graphene photocatalytic composites. Presence of defects in graphene is found to enable covalent bonding between graphene and TiO2, creating hybridised electronic states that facilitate charge transfer and hinder electron-hole recombination, and therefore enhance the photocatalytic performance of TiO2/graphene composites.
The widespread adoption of green hydrogen production through water electrolysis is currently hampered by the high cost and scarcity of state-of-the-art iridium-based catalysts. A research team from Shaoxing University and partners has developed a groundbreaking solution: a new strontium-palladium-ruthenium oxide catalyst engineered through a novel "heterojunction-doping synergy" strategy. This innovative material demonstrates exceptional performance and stability in facilitating the oxygen evolution reaction (OER), a critical bottleneck in water splitting. This achievement not only provides a cost-effective alternative to iridium but also establishes a new, generalizable blueprint for designing next-generation electrocatalysts, bringing large-scale green hydrogen production a significant step closer to reality.
The advancement of kilowatt-level laser lighting is hindered by poor thermal stability of YAG:Ce phosphors. AlN was introduced into YAG:Ce to fabricate AlN-YAG:Ce composite ceramics via powder-embedding nitrogen atmosphere sintering. The ceramic with 50 vol.% AlN achieves a thermal conductivity of 27.2 W·m-1·K-1—three times higher than pure YAG:Ce—while maintaining comparable luminescence. Under 1.3 W·mm-2 blue laser excitation, the 10 vol.% AlN-YAG:Ce ceramic delivers a luminous efficacy of 200.1 lm·W-1 and 4608 K. A 10 W blue laser prototype illuminates over 500 m, demonstrating strong potential for high-power laser-driven lighting.
Proton affinity or transfer is crucial in determining the activity and selectivity of the electroreduction of CO2. However, optimizing proton supply during CO2 reduction while simultaneously enhancing the activity of catalytic sites and inhibiting hydrogen evolution poses a significant challenge. It has been found that introduce another active site around the CO2 reduction catalytic site to supply proton for the proton process has been proved been an effective strategy to modulate the leverage relationship in electrochemical CO2 reduction (ECR).