High temperature interaction of Y4Al2O9/Y2O3 under CMAS exposure: Mechanism of outstanding corrosion resistance through composition design to accelerate reaction-induced CMAS consumption
Peer-Reviewed Publication
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A novel Y4Al2O9/Y2O3 composite exhibits substantial resistance to CMAS infiltration at both temperatures at 1300 ℃ and 1500 ℃, without notable grain-boundary penetration by CMAS glass. More importantly, the incorporation of reaction active compositions in the composite accelerated the consumption of molten CMAS constituents and reduced its corrosive activity, which is recognized as the crucial principle for composition design of anti-CMAS materials. This work provides valuable insights that guide the design of composition and advancement of superior CMAS-resistant materials.
Hypersonic vehicles face critical aerodynamic heating during flight, demanding advanced thermal protection systems (TPS). A team of Chinese researchers has developed a novel carbon-bonded carbon fiber (CBCF) composite modified with SiBCN ceramics (CBCF/SiBCN), enabling efficient in-plane heat dissipation while maintaining thermal insulation. The composite exhibits exceptional anisotropic thermal properties and mechanical strength, addressing long-standing limitations in traditional CBCF materials for aerospace TPS.
The combustion chamber temperature of the new generation aircraft engines can reach an ultra-high temperature of 1800 °C, making temperature monitoring of key components crucial. Thin-film thermocouples (TFTCs) are highly sensitive and have rapid response time; however, their upper temperature limit remains below 1800 °C. This study proposes an ultra-high temperature film thermocouple, enhanced by yttria-stabilized zirconia (YSZ) for positive film, indium oxide (In2O3) for negative film, aluminium oxide (Al2O3) for protect film. The thermocouple is designed based on temperature measurement principles, First-principles, and simulations, and it is manufactured via screen-printing. The results indicate that the maximum working temperature is 1850 ℃. In experiments with different doping ratios at 1800 ℃, the thermocouple achieves a maximum temperature electromotive force (TEMF) of 258.5 mV and a maximum Seebeck coefficient of 180.9 μV/°C, with an In2O3:YSZ92(ZrO2:Y2O3 = 92:8 wt%) ratio of 9:1 wt%. Using the lumped heat capacity method, the response time is measured at 2.8 ms, demonstrating good dynamic response characteristics. The film thermocouple is successfully utilized to measure the gas temperature of 1090 °C at the outlet of air turbine rocket engine, confirming its high-temperature operational capability. To improve the repeatability of the TFTCs without affecting their thermoelectric outputs, a CNN-LSTM-attention neural network is implemented to mitigate repeatability errors, achieving a high repeatability of 99.53%. Additionally, the compensated temperature data are compared with those obtained from a standard B-type thermocouple, showing a full-scale error of ±0.73% FS. This study provides a feasible solution for ultra-high temperature measurements.
To tackle the shortcomings of conventional nano-YSZ thermal-barrier coatings—infrared semitransparency, low nanoparticle retention, and the formation of partially melted agglomerates during plasma spraying—researchers have encased each YSZ nanoparticle in a sacrificial carbon shell that protects it from melting throughout the deposition process. Once burned off, the film leaves nano-pores that, together with the preserved nanoparticles, greatly boost infrared scattering and lower simulated metal temperatures by 111.2 K—offering a scalable route to thermal-barrier coatings with superior radiation blocking and long-term high-temperature stability.
A new study in Forest Ecosystems reveals how fire history, vegetation type, and soil features jointly influence carbon storage in boreal forests. Researchers in Norway compared pine and spruce forests across regions with different fire legacies, and they found that pine forests store nearly twice as much organic carbon as spruce forests, with charcoal carbon stocks varying by region due to fire frequency, terrain microtopography, and organic layer depth. The study highlights the importance of localized forest management strategies for sustaining carbon storage in the face of climate change.
Excessive Malassezia yeast colonization in lesional skin has been found to cause psoriasis exacerbations. This paper published in Mycology found that oxymatrine inhibits Malassezia biofilm formation and ameliorates Malassezia-associated psoriasis by modulating oxidative stress, inflammation, and apoptosis.
Researchers from Beijing Institute of Technology introduce a novel two-stage method for converting monochromatic near-infrared (NIR) images into high-quality RGB images. In the first stage, luminance information is recovered by converting NIR images into grayscale images. The second stage then restores chrominance information, transforming grayscale images into vibrant RGB images. This grayscale-assisted approach significantly improves image quality for applications such as assisted driving and security surveillance.
China’s national carbon market has become the world’s largest carbon market and is expected to be a crucial policy instrument for achieving the country’s “dual carbon” goals. The design of China’s national carbon market integrates economic theory and international experiences, and more importantly, it fully considers China’s actual situation. This is reflected in key areas such as sectoral coverage, allowance allocation, cap setting, and the MRV (Monitoring, Reporting and Verification) system. Currently, China’s national carbon market has made effective progress in several aspects, but it also faces challenges.
A research team led by Shiwei Wang at Shanghai Institute of Ceramics, Chinese Academy of Sciences, has developed a novel ultrasonic-vibration-assisted re-flow machining (URM) method for ceramic gels. This technique enables high-precision, non-destructive machining of ceramics in their wet gel state, overcoming limitations of traditional machining techniques. The method allows drilling, slotting, and removing without introducing cracks, offering a potential approach to manufacturing complex ceramic components.
Cr-Nb containing refractory high-entropy alloys (RHEAs) excel in high strength beyond 1200℃ but a low density close to Ti-based alloys, which endow them promising for applications in aero engines. However, oxidation is the bottleneck that limits their practical applications. Recently, CrNbO4 has been found to effectively protect them from oxidation. Nevertheless, little is known about this oxide. To elucidate the protection mechanism of CrNbO4 and explore its properties, we report herein for the first time the microstructure, mechanical, and thermal properties of CrNbO4.