Electrifying nitrate conversion: dual-metal-site catalysts as a game-changer for sustainable NH3 production
Peer-Reviewed Publication
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Electrochemical nitrate reduction reaction (NO3RR) emerges as a sustainable approach for converting residual nitrate pollutants into valuable ammonia under ambient conditions, offering a promising alternative to the energy-intensive Haber-Bosch process. Compared to single-metal-site electrocatalysts, dual-metal-site (DMS) electrocatalysts show synergistic effects between adjacent metal sites, effectively regulating the electronic state and enhancing the catalytic activity and selectivity for NO3RR with multi-step proton and electron transfers. Further understanding on NO3RR is of practical significance for design of efficient DMS electrocatalysts.
Understanding the structure–activity relationship of catalysts is crucial for addressing global energy and environmental challenges. A research team led by Professor Jiangwei Zhang from Inner Mongolia University presents a comprehensive review of advanced characterization techniques—including spectroscopy, microscopy, compositional analysis, and in-situ/operando methods—that enable atomic-level insights into catalytic systems. These techniques pave the way for intelligent catalyst design and real-time reaction monitoring.
Hexagonal boron nitride (h-BN) ceramics possess high thermal conductivity, excellent electrical insulation, and good thermal and chemical stability, showing great potential for high-end electronics and thermal management. Current industrial production relies on hot pressing, which limits product size and yield with high costs. Pressureless sintering is simple, low-cost, and suitable for large or complex shapes. However, due to the extremely low self-diffusion coefficient of h-BN, densification via pressureless sintering is difficult, with relative densities typically below 90%. Therefore, achieving densification of h-BN by pressureless sintering has remained a key challenge for over half a century since its first synthesis.
Hydrogen purification is a critical challenge for clean energy. The Sun and Kang’s group have now developed a novel composite membrane using a "mortar-and-brick" strategy. This membrane combines a metal-organic framework (MOF) as the "bricks" with a hydrogen-bonded organic framework (HOF) as the "mortar," creating an all-nanoporous hierarchical structure. Hetero-MOF facilitates the hetero-nucleation, and the systematic rule of HOF’s crystal growth interfered by hetero-phase is established: suppressing the homo-nucleation, balancing nucleation driving force with molecular attachment rates, and optimizing the nutrients supplement and demand. The optimized membrane shows a 562% increase in hydrogen permeance and 241% improve in hydrogen/methane selectivity compared to a pure HOF membrane, offering a new blueprint for next-generation gas separation materials that combine easy processing with high performance.
Harnessing solar energy to produce usable power is not new, but the technology is constantly evolving and improving. A major development in recent times is the use of perovskite solar cells (PSCs), which are low-weight, highly efficient, flexible solar cells using perovskite (typically a metal-halide material with a specialized structure) crystal structures to absorb light. Though a promising concept, improvements are necessary for PSCs to be able to reach their full potential. Researchers approach these improvements by introducing an additive, 1H-indole-3-carbohydrazide (1H-CBH) to effectively alleviate the main obstacle of PSCs, which are defects leading to loss of energy and efficiency in the cell.