Ligand-engineered layered solid-liquid interfaces enable fast and selective ion transport
Peer-Reviewed Publication
Welcome to theTsinghua University Press (TUP) News Page.
Below are the latest research news from TUP.
Updates every hour. Last Updated: 20-Oct-2026 19:16 ET (20-Oct-2026 23:16 GMT/UTC)
Researchers have shown that nonaqueous solvent molecules can serve as active interfacial ligands rather than passive transport media. At a layered cyano-bridged metal framework, outer-layer ligands accelerate lithium-ion solvation renewal, while interlayer ligands stabilize a low-curvature surface that strengthens anion anchoring. The cooperative interface raises lithium-ion conductivity and selectivity, and a molecular descriptor based on ligand polarity symmetry provides a route toward predictive solvent selection.
Underwater gliders can cruise for months and cover thousands of kilometres, but one glider can sample only a small slice of the ocean. A review in Ocean maps how researchers have turned these platforms into coordinated fleets for observing ocean phenomena and detecting underwater targets. It also charts the control, communication, and planning methods that could make such fleets self-healing and energy-aware.
Low-quality brines represent an abundant and valuable resource for sustainable lithium supply, but their high Mg2+ concentrations and high Mg2+/Li+ ratios make the separation of Mg2+ and Li+ particularly challenging. A research team at Tsinghua University has developed a polyelectrolyte-intercalated graphene oxide membrane with tunable interlayer spacing, in which the effective interlayer gallery width was controlled through counter-ion adsorption, enabling efficient Mg2+/Li+ separation under high Mg2+ concentrations and high Mg2+/Li+ ratios through practical pressure-driven filtration.
Stable quantum dot (QD) inks are critical yet challenging for advancing the efficiency and scalability of solution-processed optoelectronic devices. PbS-PbI2 QDs are attractive for their superior passivation and inter-dot coupling, but require strongly-coordinating alkylamine solvents which continuously etch the QDs and lead to rapid ink degradation. Research teams from Northeast Normal University in China and Jeonbuk National University in Korea reported a vapor-assisted pre-solvation strategy, extending the storage-lifetime of PbS-PbI2 QDs over 60 days, ensuring outstanding thermal robustness and demonstrating scalable manufacturing potential of QDs.
Cu-doped Er2O3 catalysts (Cu-Er2O3-x) are synthesized to overcome kinetic, selectivity and proton supply issues of CO2RR to CH4. Cu doping creates a strong built-in electric field (BIEF) via charge redistribution, shortening *H-catalyst distance, boosting water dissociation and optimizing *CHO adsorption. The best Cu-Er2O3-6 reaches 60.79% CH4 Faradaic efficiency with stable performance over 24 h. Characterizations and DFT verify BIEF accelerates proton transfer and lowers the barrier of the rate-determining *CHO→*CH2O step. This work proposes a BIEF regulation strategy to design high-selectivity CH4 electrocatalysts for carbon neutrality.