Decoupling the factors governing diffuse phase transition and relaxor-ferroelectric evolution in high-entropy tetragonal tungsten bronze ceramics
Peer-Reviewed Publication
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High-entropy design is widely used to tailor structural disorder and local polarization in ferroelectric ceramics, but whether it necessarily enhances relaxor characteristics in tetragonal tungsten bronze (TTB) systems remains unclear. Here, entropy-tunable K(NaPr)1-x(SrBa)xNb5O15 ceramics were constructed to decouple the factors governing diffuse phase transition and relaxor-ferroelectric evolution. Contrary to conventional expectations, increasing configurational entropy does not enhance relaxor behavior; instead, the system evolves from an ergodic relaxor state toward a ferroelectric-like state. This evolution is governed by crystal structure, BO6 local environment, and polar nanoregions dynamics, whereas diffuse phase transition is associated with incommensurate modulation.
The journal Materials Reports: Solidwaste and Ecomaterials (MRSE) is welcoming submissions at this time. MRSE has a mission of communicating innovative and original research, interesting and critical thinking, development, and application of various solid wastes around the world. The editorial team will consider original research, reviews, progress reports, and communications that have the concept of turning solid wastes into unhazardous, useful, functional, and valuable ecomaterials.
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