Tandem catalytic strategy enables selective upcycling of polystyrene waste into pure toluene
Peer-Reviewed Publication
Updates every hour. Last Updated: 27-Oct-2026 22:16 ET (28-Oct-2026 02:16 GMT/UTC)
Researchers have developed a tandem depolymerization and hydrogenolysis strategy that selectively converts polystyrene waste into toluene with 99 % selectivity and 83.5 wt% yield. The two‑stage process first subjects polystyrene to hydropholysis at 475 °C to generate aromatic intermediates, followed by vapor‑phase hydrogenolysis at 275 °C and 0.4 MPa over a ruthenium single‑atom modified Co₃O₄ catalyst (RuSA/Co₃O₄). The system is compatible with various disposable polystyrene‑based raw materials, delivering approximately 81 wt% yield and >99 % selectivity for toluene. This work represents a transformative paradigm for polystyrene valorization, moving from non‑selective deconstruction toward selective synthesis.
Researchers have developed a tandem depolymerization and hydrogenolysis strategy that selectively converts polystyrene waste into toluene with 99 % selectivity and 83.5 wt% yield. The two‑stage process first subjects polystyrene to hydropholysis at 475 °C to generate aromatic intermediates, followed by vapor‑phase hydrogenolysis at 275 °C and 0.4 MPa over a ruthenium single‑atom modified Co₃O₄ catalyst (RuSA/Co₃O₄). The system is compatible with various disposable polystyrene‑based raw materials, delivering approximately 81 wt% yield and >99 % selectivity for toluene. This work represents a transformative paradigm for polystyrene valorization, moving from non‑selective deconstruction toward selective synthesis.
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