From waste to value: Copper-catalyzed method converts CO₂ into high-value polymers under mild conditions
Peer-Reviewed Publication
Updates every hour. Last Updated: 28-Oct-2025 11:11 ET (28-Oct-2025 15:11 GMT/UTC)
A research team from Songshan Lake Materials Laboratory introduced a new, eco-friendly method to transform carbon dioxide (CO₂, a major greenhouse gas) into useful high-performance plastics using a simple copper-based catalyst. Conducted under mild conditions at room temperature and ambient pressure, this process efficiently incorporates CO₂ into polymer materials that can be used in packaging, sensors, biomedical devices and more. The developed polymers are highly soluble, customizable, and can be quickly modified to create multifunctional materials. This innovative approach not only offers a sustainable way to recycle CO₂ but also opens new possibilities for producing advanced materials that support environmentally friendly manufacturing and help combat climate change.
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Developing innovative resource utilization strategies to achieve sustainable recycling of waste-to-fuel is highly desirable, yet the design of cost-effective bifunctional catalysts with dual high-efficiency remains unexplored. While the Fenton-like reaction relies on enhancing peroxymonosulfate (PMS) adsorption and accelerating interfacial electron transfer to improve kinetic rates, CO2 reduction is constrained by sluggish kinetics and competing hydrogen evolution reaction. Herein, we construct a bifunctional catalyst (NiFe-BNC) featuring dual-atomic active sites by introducing boron atoms into a biomass-derived chitosan substrate rich in functional groups, which optimizes atomic coordination environments. In situ experiments and density functional theory calculations reveal that B-atom modulation facilitates carbon substrate defect enrichment, while the charge-tuning effect between metal sites and “boron electron bridge” optimizes PMS adsorption configurations. This synergistic effect facilitates the interfacial electron transfer and enhances the CO2 adsorption capacity of NiFe-BNC by 6 times that of NiFe-NC. The obtained NiFe-BNC exhibits significantly enhanced catalytic activity and selectivity, realizing 99% efficient degradation of volatile organic pollutants in the flowing phase within 2 h and stable mineralization exceeding 60%, while achieving a large current density of 1000 mA cm−2 and CO Faraday efficiency of 98% in the flow electrolytic cell. This work innovatively paves a new way for the rational design of cost-effective functional catalysts to achieve carbon cycle utilization.