Atomic-precision engineering delivers excellent stability for acidic water oxidation
KeAi Communications Co., Ltd.Peer-Reviewed Publication
Developing durable oxygen evolution reaction (OER) catalysts for acidic media is vital for advancing proton exchange membrane water electrolyzers (PEMWE). This study reveals that the stability of spinel oxide Co₃O₄ is profoundly dictated by the anchoring sites of iridium single atoms. By directly comparing iridium atoms at surface three-fold hollow sites versus lattice sites, the researchers found that lattice-embedded iridium dramatically suppresses cobalt and oxygen migration, enhances metal–oxygen covalency, and preserves structural integrity under harsh acidic conditions. These findings highlight a site-specific stabilization mechanism and provide an effective atom-level strategy for designing durable and low precious-metal OER catalysts.
- Journal
- eScience
- Funder
- National Key Research and Development Program of China, CAS Project for Young Scientists in Basic Research, National Science Fund for Distinguished Young Scholars, NSFC, Fundamental Research Funds for the Central Universities, Yulin University and the Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, International Partnership Program of Chinese Academy of Sciences, Science and Technology Development Fund (FDCT) of Macao S.A.R, Guizhou Provincial Science and Technology Projects, Fellowship of China Postdoctoral Science Foundation, Postdoctoral Fellowship Program of CPSF, Tencent Foundation through the XPLORER PRIZE