A novel strategy for highly selective ethanol synthesis from methane driven by light-driven transformation without reliability for reactive oxygen species
Peer-Reviewed Publication
Updates every hour. Last Updated: 17-Jan-2026 06:11 ET (17-Jan-2026 11:11 GMT/UTC)
Professor Zhongkui Zhao of Dalian University of Technology, in collaboration with Professor Riguang Zhang of Taiyuan University of Technology, Researcher Yuefeng Liu of the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Professor Ting Zhang of Qingdao University, and Professor Chunshan Song of the Chinese University of Hong Kong, constructed a single-atom Cu-N2O1 site with axial oxygen coordination on C3N4. Through the polar activation of the CH bond by the polar Cu-O bond, they successfully pioneered a new photocatalytic methane upgrading strategy independent of reactive oxygen species. This strategy not only significantly increased the rate of photocatalytic methane conversion to ethanol by 226 μmol/g/h under mild conditions, but also achieved an ethanol product selectivity as high as 98%. This achievement not only greatly advances the basic understanding of photocatalytic methane conversion to ethanol, but also creates a new paradigm for photocatalytic methane upgrading, successfully solving the seesaw dilemma between the liquid fuel generation rate and its selectivity in the photocatalytic methane conversion process, and providing new ideas and methods for the innovative development of future photocatalytic methane conversion. The article was published as an open access research article in CCS Chemistry, the flagship journal of the Chinese Chemical Society.
Ambient-air, moisture-assisted annealing is widely used in fabricating perovskite solar cells (PSCs). However, the inherent sensitivity of perovskite intermediate-phase to moisture—due to fast and spontaneous intermolecular exchange reaction—requires strict control of ambient humidity and immediate thermal annealing treatment, raising manufacturing costs and causing fast nucleation of perovskite films. We report herein a self-buffered molecular migration strategy to slow down the intermolecular exchange reaction by introducing a n–butylammonium bromide shielding layer, which limits moisture diffusion into intermediate-phase film. This further endows the notably wide nucleation time and humidity windows for perovskite crystallization in ambient air. Consequently, the optimized 1.68 eV-bandgap n-i-p structured PSC reaches a record-high reverse-scan (RS) PCE of 22.09%. Furthermore, the versatility and applicability of as-proposed self-buffered molecular migration strategy are certified by employing various shielding materials and 1.53 eV-/1.77 eV-bandgap perovskite materials. The n-i-p structured PSCs based on 1.53 eV- and 1.77 eV-bandgap perovskite films achieve outstanding RS PCEs of 25.23% and 19.09%, respectively, both of which are beyond of the state-of-the-art ambient-air processed PSCs.
Pancreatitis, a severe inflammatory disease of the pancreas, has long challenged clinicians due to its complex pathophysiology and limited treatment options.
Do renewables always make power cheaper? In the UK, it depends on how much is on the system. Using causal machine learning on 2018–2024 market data, researchers find wind’s causal effect is U-shaped: at low penetration, +1 GWh can reduce prices by up to £7/MWh, the effect weakens mid-range, then strengthens again at higher penetration. The impacts have grown over time as renewables’ share rose, providing an evidence base for market design and support policy. These findings support adaptive support schemes and capacity planning that reflect changing marginal value rather than one-size-fits-all assumptions.