16-Dec-2025
Unveiling non-thermal catalytic origin of direct current-promoted catalysis for energy-efficient transformation of greenhouse gases to valuable chemicals
National Institutes of Natural SciencesPeer-Reviewed Publication
Catalytic dry reforming of methane (DRM) is a key reaction for the sustainable utilization of major greenhouse gases, CO2 and CH4. However, conventional DRM often suffers from severe catalyst deactivation due to high temperature requirements. Applying direct current (DC) to catalyst materials has emerged as a promising strategy to overcome these limitations, yet the underlying DC-enhanced catalytic mechanism remains elusive. Here, we unveil the non-thermal catalytic origin of DC-applied DRM over Pd/CeO2 through multimodal operando analyses, providing a microscopic physicochemical framework for the rational design of next-generation DRM catalysts beyond the limitations of conventional thermal catalysis.
- Journal
- The Journal of Physical Chemistry Letters
- Funder
- JSPS KAKENHI, Grant-in-Aid for Early-Career Scientists, JSPS KAKENHI, Grant-in-Aid for Transformative Research Areas (A), JSPS KAKENHI, Grant-in-Aid for Scientific Research (A), JSPS KAKENHI, Grant-in-Aid for Specially Promoted Research, JSPS KAKENHI, Fund for the Promotion of Joint International Research (International Leading Research), JST CREST, Japan, JST ACT-X, Japan, BL3U of UVSOR Synchrotron Facility, Institute for Molecular Science (IMS program), Demonstration Project of Innovative Catalyst Technology for Decarbonization through Regional Resource Recycling, the Ministry of the Environment, Japan