A mechanically tunable molecular switch for circularly polarized light emission
Peer-Reviewed Publication
Updates every hour. Last Updated: 21-Oct-2026 20:16 ET (22-Oct-2026 00:16 GMT/UTC)
A force-responsive molecular system that reversibly switches circularly polarized luminescence (CPL) on and off at the single-molecule level has been developed, as reported by researchers from Japan. The team designed a platform consisting of a supramolecular mechanophore embedded in a polymer network gel, whose CPL emission is switched via swelling with a solvent. This approach provides an accurate way to evaluate force-induced CPL and expands the possibilities for next-generation mechanically responsive optical materials.
The ability to read facial expressions is a vital part of social communication and can be influenced by the observer’s emotional state. In a study, researchers examine whether positive emotions, induced by watching a comedy video, can help improve observers’ sensitivity to subtle positive facial expressions. The study also explores whether this effect differs when faces are covered by masks and whether individual traits, such as empathy and depressive tendencies, are related to these differences.
How the well-known "invar effect" -- near-zero thermal expansion -- plays out separately in each element of complex, cobalt-containing stainless invar alloys (iron, cobalt, chromium, nickel) has been unclear, particularly how it responds to small shifts in the iron-to-cobalt ratio. Researchers combined synchrotron element-specific X-ray absorption spectroscopy with dilatometry and atomic-scale Monte Carlo simulation on several face-centered-cubic (fcc) alloy samples with slightly different iron-to-cobalt ratios, finding that both iron and cobalt locally suppress thermal expansion but iron's contribution is larger, and that this balance shifts measurably even with small compositional changes; a non-annealed, body-centered-cubic version of the same alloy instead showed ordinary, positive thermal expansion, confirming the invar behavior is specific to the annealed fcc structure. These findings refine understanding of element-specific magnetovolume behavior in stainless invar alloys, distinguishing them from classic iron-nickel invar and the related Kovar alloy where iron dominates more strongly, though the authors caution that the iron-to-cobalt ratio alone does not fully explain the observed trends across all samples tested, and the conclusions rest on a small set of compositions examined only between 30 and 400 K.
Researchers found that eye-level neighborhood characteristics and residents’ perceptions of their surrounding environment are associated with sleep health among working adults in Tokyo. Streetscapes with a greater sense of enclosure and perceived safety were linked to longer sleep duration, while greenery may support sleep indirectly by enhancing feelings of safety.
Osaka Metropolitan University researchers successfully synthesized spherical Rh-Pd-Ir-Pt-Au HEA NPs with a mean diameter of approximately 10 nm in an aqueous mixed metal salt solution without any additional chemical reductants.
Researchers from the University of Osaka found that hepatocyte-derived extracellular vesicles treated with sPLA2 (SPLEVs) induce a lipid counterstorm that counteracts cytokine storm in mice with acute respiratory distress syndrome. SPLEVs also demonstrated significant beneficial effects in mouse models of sepsis, coagulopathy, liver injury, colitis, and pneumonia. As lysophosphatidylglycerols were identified as a key mediator of SPLEV activity, these findings suggest a promising approach for developing inexpensive, cell-free anti-inflammatory treatments.