Low-cost, high-efficiency electrochemical separation of stable sulfur isotopes
Beijing Institute of Technology Press Co., LtdIsotopes are atoms of the same element with identical proton numbers but different neutron counts. Stable isotopes, with half-lives longer than 1015 years, undergo negligible radioactive decay. For elements of the third Period and beyond, their isotopes usually show minor differences in physical properties and are considered chemically identical in many previous studies.
The assumption does not always hold.
A research team led by Prof. Sen Xin from the Institute of Chemistry, Chinese Academy of Sciences have recently revealed that two stable sulfur isotopes (34S and 32S) exhibit significant differences in both kinetics and thermodynamics of participating the electrode reactions in a rechargeable Li-S battery. The (dis)charge process of Li-S batteries usually involves generation and dissolution of high-order lithium polysulfide intermediates (Li2Sn, 4≤n≤8) at the cathode-electrolyte interface, and diffusion of Li2Sn through the liquid electrolyte to reach the Li-metal anode. The above process forms the main reason for rapid capacity decline of the S cathode and exothermic parasitic reactions on the surface of Li anode. By employing the time-of-flight secondary ion mass spectrometry and inductively coupled plasma-mass spectrometry, the team has proven that the 34S-based polysulfides (Li234Sn) migrate slower than the 32S-based polysulfides, which accounts for improved battery performance and isotope fractionation at both electrodes.
- Journal
- Energy Material Advances
- Funder
- National Natural Science Foundation of China, Beijing Natural Science Foundation, Energy Revolution S&T Program of Yulin Innovation Institute of Clean Energy