Add a twist to π-molecules! A new design strategy for organic semiconductor materials
National Institutes of Natural SciencesPeer-Reviewed Publication
A research team led by Associate Professor Yasushi Segawa, graduate students Mai Nagase (at the time of the research) and Rui Yoshida, and technical staff member Sachiko Nakano of the Institute for Molecular Science (IMS) and SOKENDAI (The Graduate University for Advanced Studies), together with Associate Professor Takashi Hirose of Kyoto University's Institute for Chemical Research, has synthesized three-dimensionally shaped molecules containing an internal twist and shown that they possess the properties of organic semiconductors. By introducing methyl groups into a planar molecule containing several thiophene units and forcing it into a twisted conformation, the team created a solid-state structure in which electricity can flow three-dimensionally. The molecule was verified to act as an organic semiconductor in an organic field-effect transistor, paving the way for next-generation electronic devices.
These results were published online in the Royal Society of Chemistry journal Chemical Communications on 19 June 2025.
- Journal
- Chemical Communications
- Funder
- JST FOREST Program, JSPS KAKENHI Grant-in-Aid for Scientific Research (B), Murata Science and Education Foundation, Iketani Science and Technology Foundation, Foundation of Public Interest of Tatematsu