Ice mixed with amino acids stores methane in minutes
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While molecular cages offer high selectivity, previous versions lacked visible-light sensitivity, hindering their use in mild photochemical synthesis. We engineered a platinum(II)-based M6L4 cage that acts as a visible-light-responsive nanoreactor, achieving perfect stereo- and site-selective cross-[2+2] cycloadditions of inert substrates. This innovation enabled the first catalytic cross-[2+2] cycloaddition using supramolecular confinement, opening new avenues for highly controlled, light-driven organic synthesis.
CAS Academician, Prof. Jihong Yu, and her team from Jilin University developed a post-treatment strategy based on metal replacement reaction using commercial ZSM-5 zeolite as a carrier, and successfully encapsulated a highly active PtCu alloy catalyst in the pores of the zeolite. In the study, Cu²⁺ ions were first introduced into the pores of the zeolite through ion exchange, and then reduced at high temperature to form a Cu@MFI intermediate; then the Pt component was introduced through a metal replacement reaction, and a PtCu alloy was formed in the pores of the zeolite through high temperature reduction. The prepared PtCu₅@MFI-K (Pt/Cu=1/5) showed excellent catalytic performance in the propane dehydrogenation reaction, with a propane conversion rate of 49.7%, a propylene selectivity of more than 90%, and good cyclic stability. This study provides a new low-cost and efficient synthesis strategy for the development of high-performance alloy@zeolite catalysts. These results were published as an open access article in CCS Chemistry, the flagship journal of the Chinese Chemical Society.