11-Mar-2025
Catching aromaticity in the act: direct real-time tracking of how ‘excited-state aromaticity’ drives molecular shape changes
National Institutes of Natural SciencesPeer-Reviewed Publication
Scientists have achieved the first real-time visualization of how "excited-state aromaticity" emerges within just hundreds of femtoseconds and then triggers a molecule to change from bent to planar structure in a few picoseconds. By combining ultrafast electronic and vibrational spectroscopies, the team captured these fleeting structural changes at the molecular level and showed that aromaticity appears before--and then drives--the structural planarization. Their findings lay the groundwork for designing more efficient photoactive materials, such as sensors and light-driven molecular switches, by leveraging the power of aromaticity in excited states.
- Journal
- Journal of the American Chemical Society
- Funder
- JSPS KAKENHI Grant-in-Aid for Scientific Research(B), JSPS Research Fellowship for Young Scientists, JST FOREST Program, JST PRESTO Program, Inoue Foundation for Science, Inoue Science Research Award, The Morino Foundation for Molecular Science, Research Center for Computational Science, Okazaki, Japan, "Advanced Research Infrastructure for Materials and Nanotechnology in Japan (ARIM)" of the Ministry of Education, Culture, Sports, Science and Technology (MEXT)