Porphyrin–based covalent organic frameworks with undulated layers for efficient photocatalytic CO2 reduction
Peer-Reviewed Publication
Updates every hour. Last Updated: 24-Apr-2025 21:08 ET (25-Apr-2025 01:08 GMT/UTC)
Two-dimensional porphyrin-based COFs show great promise for photocatalytic CO2 reduction, yet their π-π stacking often impedes active site exposure and charge transfer. Researchers developed a series of porphyrin COFs with tunably twisted linkers. The N-N-linked twisted unit in NN-Por-COF creates a remarkably undulating layered structure that enhances mass transport and exposes more active sites, while simultaneously modulating the electronic structure of cobalt-porphyrin to reduce reaction barriers. This dual structural and electronic optimization yields outstanding photocatalytic performance, achieving CO production rates of 22.38 and 3.02 mmol g−1 h−1 under pure and 10% CO2, respectively, surpassing most porphyrin-based photocatalysts.
Recently, the team of Prof. Nishuang Liu and Prof. Yihua Gao from Huazhong University of Science and Technology has reviewed the recent advances in self-powered sensors based on ionic hydrogels. The review was published in Research as “Recent Advances in Self-Powered Sensors Based on Ionic Hydrogels”. This review systematically summarizes the self-powered mechanism of ionic hydrogel self-powered sensors, structural engineering related to device and material properties, and related applications, and discusses the challenges and future development of ionic hydrogel self-powered sensors.
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