When catalysis meets batteries: How a small molecule rewrites the fate of zinc anodes in aqueous electrolytes
Peer-Reviewed Publication
Updates every hour. Last Updated: 2-May-2026 02:16 ET (2-May-2026 06:16 GMT/UTC)
This study cross-applies d-band center theory from catalysis to stabilize zinc anodes in aqueous electrolytes. By adding oxalic acid, the d-band center of Zn is downshifted, fundamentally weakening hydrogen adsorption and suppressing hydrogen evolution. Concurrently, it optimizes the Zn2+ solvation sheath, minimizing byproduct formation. The Zn||I2 battery enables a high Coulombic efficiency of and retaining 92.8% capacity after 10,000 cycles. This work pioneers a new paradigm for stabilizing metal anodes via surface electronic structure modulation.
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