Boosting cumene hydrogen transfer via a Ru-based porphyrin covalent organic framework for tandem air epoxidation of olefins
Peer-Reviewed Publication
Updates every hour. Last Updated: 30-Apr-2026 13:16 ET (30-Apr-2026 17:16 GMT/UTC)
As an important class of versatile organic compounds and reactive intermediates, epoxides are widely used in pharmaceuticals, pesticides, coatings, and other fields. They have high chemical activity and can be further converted into other high-value chemicals. Thus, the large-scale application and the huge market demands have attracted significant attention from numerous enterprises and research institutions.
Flexible electronics have been drawing significant attention for healthcare applications and show great promise for monitoring of blood circulation (e.g., postoperative monitoring of free flaps). However, existing methods for design and fabrication of interfaces with human skin still cannot meet the challenging clinical requirements of superior adhesion during monitoring and avoiding wound damage during peel-off. Now, writing in the journal National Science Review, a team of researchers from China and Singapore proposes a soft biosensor with universal responsive hydrogel interfaces for detecting blood circulation complications. They develop thermoresponsive and printable hydrogel inks to achieve rapidly high-precision patterning and wide-range adhesion regulation of interface layers. In clinical cases, the hydrogel biosensor can establish robust hydrogel/flap skin coupling for high-fidelity signal acquisition during monitoring, and ensure benign detachment to prevent tissue injury after monitoring. They achieve precise arterial perfusion monitoring based on the perfusion index (PI) via an 810 nm light source. Additionally, they propose a new metric, the balance index (BI), to monitor venous congestion. By analyzing BI, PI, and skin temperature, the biosensor enables accurate detection and differentiation of blood circulation complications.
A research team from Huazhong University of Science and Technology has developed a novel orbital modulation strategy to suppress anti-site defects in NASICON-type Na3MnTi(PO4)3 cathode for sodium-ion batteries. By Li doping to construct Li–O–Mn configuration, the strategy effectively enhances Mn–O covalent interaction and elevates Mn defect formation energy, thus eliminating voltage hysteresis caused by anti-site defects. The optimized Na2.97Li0.03MnTi(PO4)3 cathode achieves ultra-long cycling stability, excellent rate performance and wide-temperature adaptability, and the assembled pouch-type full cell further verifies its practical application potential. This study provides a new electronic structure regulation approach for the design of high-performance sodium-ion battery cathodes, paving the way for the development of low-cost and sustainable energy storage technologies.
What if nature’s tiny wonders—waterspider legs and fish scales—hold the key to better energy storage? Researchers have turned these biological structures into a Janus air electrode, unlocking zinc-air batteries with 239.3 mW cm−2 peak power density and exceptional cycling stability.
Single-polarization single-mode (SPSM) fibers have been one of the most promising candidates for robust and stable terahertz (THz) transmission. Towards this goal, Scientist in China proposed that Dirac vortex modes (DVWs) enabled by Kekulé phase modulation provide a new guiding mechanism for THz photonic crystal fibers, combining ultra-broad bandwidth, strong field localization, low-loss potential, and polarization stability. Moreover, the experimental characterization techniques developed in this work offer a valuable reference for investigating THz waveguide modes.