Giving doctors an AI-powered head start on skin cancer
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Updates every hour. Last Updated: 17-Aug-2025 23:11 ET (18-Aug-2025 03:11 GMT/UTC)
Recently, the team led by Academician Wei-Hong Zhu at East China University of Science and Technology proposed a novel photo-rearrangement reaction of diarylethenes induced by intramolecular proton transfer (IPT), while exploring the reactivity of active carbon sites in diarylethene systems. In this study, published in CCS Chemistry, aldehyde and carboxyl groups were innovatively introduced at the active carbon positions, revealing distinct photoresponsive behaviors. The dialdehyde-substituted system exhibited typical reversible photochromism, whereas the dicarboxylate-substituted counterpart underwent an unexpected photorearrangement to yield polycyclic aromatic structures. Mechanistic studies, including transient absorption spectroscopy and density functional theory (DFT) calculations, demonstrated that the rearrangement proceeds through electrocyclization followed by an IPT-driven decarboxylation process. This work opens a new pathway for light-induced synthesis of polycyclic aromatic hydrocarbons and highlights potential applications in molecular modification, photoreaction mechanisms, and synthetic photochemistry.
A group of researchers on an oceanic research expedition ran into a hurricane and turned it to their advantage, studying the water in the storm's wake. Professor Michael Beman and his team discovered that powerful storms draw deep-water low-oxygen zones closer to the ocean's surface, along with the organisms that inhabit them, creating smorgasbords for some sea creatures but potentially endangering those that depend on higher oxygen concentrations for survival.
Co-packaged optics (CPO) technology requires reliable laser sources, either integrated or external, for operation. Since integrated laser sources are associated with reliability challenges, researchers are increasingly exploring CPO systems with external sources. Recently, polymer waveguides fabricated on glass-epoxy substrates have emerged as a reliable solution for transmitting laser signals from external sources to photonic circuits. Researchers from Japan have now demonstrated the suitability of these waveguides for use in CPO systems.