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Peer-Reviewed Publication
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Layered double hydroxides (LDHs) are emerging as promising electrocatalysts for the oxygen evolution reaction (OER), a key barrier in clean hydrogen production. However, their catalytic performance has long been restricted by limited active sites, sluggish electron transfer, and structural instability under operational conditions. A new review summarizes how electronic defect engineering, including vacancy creation, heteroatom doping, single-atom incorporation and lattice modulation, which reconfigures electron distribution, enhances active site exposure, accelerates reaction kinetics, and strengthens catalytic durability. The work highlights strategies that effectively lower OER overpotential and improve stability by tuning LDH atomic coordination environments, providing a unified framework for the design of next-generation high-performance water-splitting catalysts.