Robust, thermally stable and impurity-tolerant aluminum-based catalyst system for polylactide production under industrial conditions
Peer-Reviewed Publication
Updates every hour. Last Updated: 19-Jun-2025 00:10 ET (19-Jun-2025 04:10 GMT/UTC)
In a paper published in Polymer Science & Technology, an international team of scientists
designed and synthesized tetracoordinate aluminum methyl complexes bearing (amidoalkyl)pyridine−phenolate (AmPyPh) pincers for industrial L-LA polymerizations. Then they further investigated the electronic and steric effects of the substituents in different positions on catalytic activity with assistance of density functional theory calculation. The results indicated the synthesized AmPyPh-Al catalysts exhibited excellent thermostability as well as good protonic tolerance, which could effectively promote the polymerization of technical grade L-LA without further purification under industrial-relevant conditions (150−180 °C, in melt and bulk) with catalyst concentrations as low as 0.0005 mol % (monomer/catalyst feed ratio = 200000:1). Meanwhile, these novel Al complexes could suppress the epimerization side reaction under harsh conditions and afforded semicrystalline PLLA. This study is led by Xiaosa Zhang (College of Science, Shenyang University of Chemical Technology, Shenyang 110142, China) and Bin Wang (Tianjin Key Laboratory of Composite & Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China).
An Osaka Metropolitan University researcher conducted a survey on the use of private wells during the 2018 Western Japan floods in Kure City, Hiroshima Prefecture, which was affected by water supply disruptions.
Although extremely flammable, cotton is one of the most commonly used textiles due to its comfort and breathable nature. However, in a single step, researchers from Texas A&M University can reduce the flammability of cotton using a polyelectrolyte complex coating.