Maintaining high piezoelectric performance at porosity of 92%: Three-dimensionally interconnected porous ceramics enables highly sensitive piezoelectric response
Peer-Reviewed Publication
Updates every hour. Last Updated: 2-Apr-2026 21:15 ET (3-Apr-2026 01:15 GMT/UTC)
Porous piezoelectric ceramics exhibit strong potential for sensing weak mechanical stimuli. However, the intrinsic coupling between the piezoelectric charge coefficient (d₃₃) and dielectric constant (εᵣ) limits energy conversion efficiency. Here, a fully open, three-dimensionally interconnected PZT-based porous ceramic (3D-PPC) is developed to overcome this constraint. Despite an ultrahigh porosity of 92%, the material retains a high d₃₃ (~470 pC/N), while εᵣ is significantly reduced (~140), leading to a ~14-fold enhancement in g₃₃ (~380 × 10-3 V·m/N). This performance arises from synergistic effects of heterogeneous stress/electric fields, multiscale domain structures, and defect engineering, demonstrating that 3D interconnected porosity actively modulates local polarization behavior.
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