Developing high-energy, stable all-solid-state lithium batteries using aluminum-based anodes and high-nickel cathodes
Peer-Reviewed Publication
Updates every hour. Last Updated: 5-Jul-2025 00:10 ET (5-Jul-2025 04:10 GMT/UTC)
Aluminum (Al) exhibits excellent electrical conductivity, mechanical ductility, and good chemical compatibility with high-ionic-conductivity electrolytes. This makes it more suitable as an anode material for all-solid-state lithium batteries (ASSLBs) compared to the overly reactive metallic lithium anode and the mechanically weak silicon anode. This study finds that the pre-lithiated Al anode demonstrates outstanding interfacial stability with the Li6PS5Cl (LPSCl) electrolyte, maintaining stable cycling for over 1200 h under conditions of deep charge–discharge. This paper combines the pre-lithiated Al anode with a high-nickel cathode, LiNi0.8Co0.1Mn0.1O2, paired with the highly ionic conductive LPSCl electrolyte, to design an ASSLB with high energy density and stability. Using anode pre-lithiation techniques, along with dual-reinforcement technology between the electrolyte and the cathode active material, the ASSLB achieves stable cycling for 1000 cycles at a 0.2C rate, with a capacity retention rate of up to 82.2%. At a critical negative-to-positive ratio of 1.1, the battery’s specific energy reaches up to 375 Wh kg-1, and it maintains over 85.9% of its capacity after 100 charge–discharge cycles. This work provides a new approach and an excellent solution for developing low-cost, high-stability all-solid-state batteries.
Hygroscopic hydrogel is a promising evaporative-cooling material for high-power passive daytime cooling with water self-regeneration. However, undesired solar and environmental heating makes it a challenge to maintain sub-ambient daytime cooling. While different strategies have been developed to mitigate heat gains, they inevitably sacrifice the evaporation and water regeneration due to highly coupled thermal and vapor transport. Here, an anisotropic synergistically performed insulation-radiation-evaporation (ASPIRE) cooler is developed by leveraging a dual-alignment structure both internal and external to the hydrogel for coordinated thermal and water transport. The ASPIRE cooler achieves an impressive average sub-ambient cooling temperature of ~ 8.2 °C and a remarkable peak cooling power of 311 W m-2 under direct sunlight. Further examining the cooling mechanism reveals that the ASPIRE cooler reduces the solar and environmental heat gains without comprising the evaporation. Moreover, self-sustained multi-day cooling is possible with water self-regeneration at night under both clear and cloudy days. The synergistic design provides new insights toward high-power, sustainable, and all-weather passive cooling applications.
The findings, presented today at the ESOT Congress 2025, mark a significant step forward in overcoming the biggest challenge in xenotransplantation: rejection by the human immune system.
Scientists from Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, have developed a novel ultrasound-driven therapy that activates dormant cancer drugs directly inside tumors. By combining low-intensity ultrasound with specially designed nanoparticles, the team achieved a 99% tumor suppression rate and 66.7% cure rate in mice. This non-invasive approach minimizes side effects and could revolutionize targeted cancer treatment.
The paper published in SCIENCE CHINA Chemistry systematically summarizes the research progress and innovative strategies for improving the performance of NaₓTMO₂ cathode materials through interface regulation engineering in recent years. This work reveals the enhancement mechanisms of interface engineering, such as inorganic/organic coatings, heterogeneous interface phase designing, and surface doping. The phase evolution behaviors, ion-transfer kinetics, and electrochemical properties of NaₓTMO₂ resulted from interfacial modulations are concluded in depth.
Urea is a fundamental industrial chemical and may have played a central role in the origin of life.
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Scientists at St. Jude Children’s Research Hospital unveiled a tool to capture protein-water networks and their contribution to drug-binding sites.