Capturing an elusive step in molecular sandwich making
Okinawa Institute of Science and Technology (OIST) Graduate UniversityPeer-Reviewed Publication
Since their discovery in the 1950s, metallocenes — chemical compounds where a metal atom sits ‘sandwiched’ between two carbon rings — have been at the heart of organometallic chemistry research, finding applications in catalysis, materials design, energy, sensing, drug delivery and more. Yet knowledge of their formation has been limited, due to the transient nature of their unstable intermediates.
Published in the Journal of the American Chemical Society (JACS), researchers from the Okinawa Institute of Science and Technology (OIST) have reported the first full structural characterization of a doubly ring-slipped reaction intermediate in the formation of a metallocene. With its unusual structure, the characterization provides new evidence of how metallocenes may form, break and react, presenting design opportunities for stimuli-responsive, metallocene-based materials for a wide variety of potential applications.
- Journal
- Journal of the American Chemical Society
- Funder
- Japan Society for the Promotion of Science, Okinawa Institute of Science and Technology Graduate University, Japan Society for the Promotion of Science