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Enhanced Molecular Sensing with Overcoupled Resonators: A Novel Approach to Plasmonic Nanantenna Design
Shanghai Jiao Tong University Journal CenterPlasmonic nanoantennas provide unique opportunities for precise control of light-matter coupling in surface-enhanced infrared absorption (SEIRA) spectroscopy, but most of the resonant systems realized so far suffer from the obstacles of low sensitivity, narrow bandwidth, and asymmetric Fano resonance perturbations. Here, we demonstrated an overcoupled resonator with a high plasmon-molecule coupling coefficient (µ) (OC-Hµ resonator) by precisely controlling the radiation loss channel, the resonator-oscillator coupling channel, and the frequency detuning channel. We observed a strong dependence of the sensing performance on the coupling state, and demonstrated that OC-Hµ resonator has excellent sensing properties of ultra-sensitive (7.25% nm-1), ultra-broadband (3-10 µm), and immune asymmetric Fano lineshapes. These characteristics represent a breakthrough in SEIRA technology and lay the foundation for specific recognition of biomolecules, trace detection, and protein secondary structure analysis using a single array (array size is 100 × 100 µm2). In addition, with the assistance of machine learning, mixture classification, concentration prediction and spectral reconstruction were achieved with the highest accuracy of 100%. Finally, we demonstrated the potential of OC-Hµ resonator for SARS-CoV-2 detection. These findings will promote the wider application of SEIRA technology, while providing new ideas for other enhanced spectroscopy technologies, quantum photonics and studying light-matter interactions.
- Journal
- Nano-Micro Letters
Frameworks for the future: PBA-templated nanocomposites for next-generation alkali-ion batteries
Shanghai Jiao Tong University Journal CenterLithium-ion batteries (LIBs) have dominated the portable electronic and electrochemical energy markets since their commercialisation, whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries (AIBs) including sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs). Owing to larger ion sizes of Na+ and K+ compared with Li+, nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium storage. With enticing open rigid framework structures, Prussian blue analogues (PBAs) remain promising self-sacrificial templates for the preparation of various nanocomposites, whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal decomposition. This review focuses on the recent progress of PBA-derived nanocomposites from their fabrication, lithium/sodium/potassium storage mechanism, and applications in AIBs (LIBs, SIBs, and PIBs). To distinguish various PBA derivatives, the working mechanism and applications of PBA-templated metal oxides, metal chalcogenides, metal phosphides, and other nanocomposites are systematically evaluated, facilitating the establishment of a structure–activity correlation for these materials. Based on the fruitful achievements of PBA-derived nanocomposites, perspectives for their future development are envisioned, aiming to narrow down the gap between laboratory study and industrial reality.
- Journal
- Nano-Micro Letters
Crystallization modulation and dual passivation strategy for enhancing the performance of perovskite/CuIn(Ga)Se2 tandem solar cells
Shanghai Jiao Tong University Journal CenterTwo-terminal (2-T) perovskite (PVK)/CuIn(Ga)Se2 (CIGS) tandem solar cells (TSCs) have been considered as an ideal tandem cell because of their best bandgap matching regarding to Shockley-Queisser (S-Q) limits. However, the nature of the irregular rough morphology of commercial CIGS prevents people from improving tandem device performances. In this paper, D-homoserine lactone hydrochloride is proven to improve coverage of PVK materials on irregular rough CIGS surfaces and also passivate bulk defects by modulating the growth of PVK crystals. In addition, the minority carriers near the PVK/C60 interface and the incompletely passivated trap states caused interface recombination. A surface reconstruction with 2-thiopheneethylammonium iodide and N,N-dimethylformamide assisted passivates the defect sites located at the surface and grain boundaries. Meanwhile, LiF is used to create this field effect, repelling hole carriers away from the PVK and C60 interface and thus reducing recombination. As a result, a 2-T PVK/CIGS tandem yielded a power conversion efficiency of 24.6% (0.16 cm2), one of the highest results for 2-T PVK/CIGS TSCs to our knowledge. This validation underscores the potential of our methodology in achieving superior performance in PVK/CIGS tandem solar cells.
- Journal
- Nano-Micro Letters
Co/Co3O4@N-doped carbon nanosheets with gradient magnetic heterointerfaces: Optimizing impedance matching and energy dissipation for enhanced electromagnetic wave absorption
Shanghai Jiao Tong University Journal CenterGradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching, adjusting dielectric/magnetic resonance and promoting electromagnetic (EM) wave absorption, but still exist a significant challenging in regulating local phase evolution. Herein, accordion-shaped Co/Co3O4@N-doped carbon nanosheets (Co/Co3O4@NC) with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and low-temperature oxidation process. The results indicate that the surface epitaxial growth of crystal Co3O4 domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components, which are beneficial for optimizing impedance matching and interfacial polarization. Moreover, gradient magnetic heterointerfaces simultaneously realize magnetic coupling, and long-range magnetic diffraction. Specifically, the synthesized Co/Co3O4@NC absorbents display the strong electromagnetic wave attenuation capability of -53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz, both are superior to those of single magnetic domains embedded in carbon matrix. This design concept provides us an inspiration in optimizing interfacial polarization, regulating magnetic coupling and promoting electromagnetic wave absorption.
- Journal
- Nano-Micro Letters
Ten actions to reduce discrimination and stigma faced by women during the menopause
Universitat Oberta de Catalunya (UOC)A new open access study published in Frontiers in Reproductive Health by Clara Selva Olid, researcher at the Behavioural Design Lab (BDLab), which is affiliated to the UOC's research unit on Digital Health, Health and Well-being, has found that implementing public actions in the political, social and organizational spheres can help reduce discrimination and social stigma, counteract the lack of attention given to this stage of life and significantly improve both quality of life and the healthcare received by women.
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- Frontiers in Reproductive Health
Energy transition and environmental policies: Their impact on BRICS’ ecological footprint
Higher Education PressA new study published in Engineering explores how energy transition, different types of environmental policies, and income affect the ecological footprint in BRICS countries. Using data from 2000—2020 and the KRLS approach, the research finds varied impacts across these countries. The results offer practical insights for policymakers aiming to enhance environmental sustainability in BRICS nations.
- Journal
- Engineering
Seeing pedestrians, lorries and signs are among the aspects that drivers find most stressful
Universitat Oberta de Catalunya (UOC)A study in which the Universitat Oberta de Catalunya (UOC) took part analyses how visual elements influence drivers' stress levels, and identifies factors that negatively affect the driving experience. Its findings pave the way for the development of smart driving assistants and the planning of city streets with fewer stress triggers.
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- IEEE Transactions on Affective Computing
Van der Waals bilayers: Monolayer stiffness stabilizes ferroelectricity above RT
Advanced Institute for Materials Research (AIMR), Tohoku UniversityCertain 2D van der Waals bilayers, such as WTe₂ and h-BN, exhibit sliding ferroelectricity, yet its stability above room temperature remained unexplained. AIMR researchers developed a thermodynamic model linking this stability to monolayer stiffness. Their findings reveal a soft “sliding phonon” governing the phase transition, with implications for next-generation nanoelectronics.
- Journal
- Physical Review Letters
Lab in a tube: Monitoring soil chemistry without disturbing it
Aarhus UniversityResearchers from Aarhus University have developed MARTINIS – a portable, low-cost, automatic lab that monitors soil chemistry in real time using planar optodes. The system can track oxygen and pH levels in situ without disturbing the soil. It enables detailed analysis of soil dynamics, supports climate research, and may inform sustainable farming practices. The open-source technology has been field-tested and is now being further developed for broader application.
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- Sensors and Actuators
- Funder
- Danmarks Grundforskningsfond