Spectral slimming for single-nanoparticle plasmons
Peer-Reviewed Publication
Updates every hour. Last Updated: 2-Apr-2026 23:16 ET (3-Apr-2026 03:16 GMT/UTC)
Researchers have developed a new strategy to overcome a long-standing limitation in plasmonic loss by reshaping light–matter interactions through substrate engineering.
Aqueous zinc-ion batteries (AZIBs) have garnered considerable attention as promising post-lithium energy storage technologies owing to their intrinsic safety, cost-effectiveness, and competitive gravimetric energy density. However, their practical commercialization is hindered by critical challenges on the anode side, including dendrite growth and parasitic reactions at the anode/electrolyte interface. Recent studies highlight that rational electrolyte structure engineering offers an effective route to mitigate these issues and strengthen the electrochemical performance of the zinc metal anode. In this review, we systematically summarize state-of-the-art strategies for electrolyte optimization, with a particular focus on the zinc salts regulation, electrolyte additives, and the construction of novel electrolytes, while elucidating the underlying design principles. We further discuss the key structure–property relationships governing electrolyte behavior to provide guidance for the development of next-generation electrolytes. Finally, future perspectives on advanced electrolyte design are proposed. This review aims to serve as a comprehensive reference for researchers exploring high-performance electrolyte engineering in AZIBs.
Aqueous zinc-ion batteries (AZIBs) offer a safe, cost-effective, and high-capacity energy storage solution, yet their performance is hindered by interfacial challenges at the Zn anode, including hydrogen evolution, corrosion, and dendritic Zn growth. While most studies focus on regulating Zn2+ solvation structures in bulk electrolytes, the evolution of interfacial solvation—where Zn2+ undergoes desolvation and deposition—remains insufficiently explored. Here, we introduce sulfated nanocellulose (SNC), an anion-rich biopolymer, to tailor the interfacial solvation structure without altering the bulk electrolyte composition. Using in situ attenuated total reflection Fourier transform infrared spectroscopy and fluorescence interface-extended X-ray absorption fine structure, we reveal that SNC facilitates the formation of a low-coordinated Zn2+ solvation shell at the interface by weakening H2O coordination. This transformation is driven by electrostatic interactions between Zn2+ and anchored sulfate groups, thereby reducing water activity, improving interfacial stability during charge/discharge, and suppressing parasitic reactions. Consequently, a high average coulombic efficiency of 99.6% over 500 cycles in Zn|Ti asymmetric cells and 1.5 Ah pouch cells (13.4 mg cm−2 loading, remained stable over 250 cycles) were achieved in SNC-induced AZIBs. This work underscores the importance of interfacial solvation structure engineering—beyond traditional bulk electrolyte design—in enabling practical, high-performance AZIBs.
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