Single-atom engineering prevents voltage decay in next-generation lithium-ion batteries
Peer-Reviewed Publication
Updates every hour. Last Updated: 5-Apr-2026 13:15 ET (5-Apr-2026 17:15 GMT/UTC)
Lithium-rich layered oxides (LRLOs) offer exceptionally high capacities but suffer rapid energy loss because of irreversible migration of transition-metal (TM) ions during cycling, triggering oxygen release and voltage decay. This study presents a breakthrough strategy: using trace dopants (only 0.75 at.% W⁶⁺) placed precisely at tetrahedral sites in the lithium layer. These isolated single dopants exert long-range Coulomb repulsion, suppressing both in-plane and out-of-plane TM migration across a ~2-nm region. As a result, cation ordering is preserved over 250 cycles, oxygen release is significantly reduced, and voltage decay drops to just 0.75 mV per cycle. This work provides a new atom-efficient pathway for stabilizing high-energy LRLO cathodes.
Developing durable oxygen evolution reaction (OER) catalysts for acidic media is vital for advancing proton exchange membrane water electrolyzers (PEMWE). This study reveals that the stability of spinel oxide Co₃O₄ is profoundly dictated by the anchoring sites of iridium single atoms. By directly comparing iridium atoms at surface three-fold hollow sites versus lattice sites, the researchers found that lattice-embedded iridium dramatically suppresses cobalt and oxygen migration, enhances metal–oxygen covalency, and preserves structural integrity under harsh acidic conditions. These findings highlight a site-specific stabilization mechanism and provide an effective atom-level strategy for designing durable and low precious-metal OER catalysts.
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