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Updates every hour. Last Updated: 1-Apr-2026 06:15 ET (1-Apr-2026 10:15 GMT/UTC)
Defect-tuned layered double hydroxides open new path for clean energy catalysts
KeAi Communications Co., Ltd.Layered double hydroxides (LDHs) are emerging as promising electrocatalysts for the oxygen evolution reaction (OER), a key barrier in clean hydrogen production. However, their catalytic performance has long been restricted by limited active sites, sluggish electron transfer, and structural instability under operational conditions. A new review summarizes how electronic defect engineering, including vacancy creation, heteroatom doping, single-atom incorporation and lattice modulation, which reconfigures electron distribution, enhances active site exposure, accelerates reaction kinetics, and strengthens catalytic durability. The work highlights strategies that effectively lower OER overpotential and improve stability by tuning LDH atomic coordination environments, providing a unified framework for the design of next-generation high-performance water-splitting catalysts.
- Journal
- eScience
- Funder
- National Natural Science Foundation of China, China Postdoctoral Science Foundation, Natural Science Foundation Project for Outstanding Youth of Henan Province, Nuclear Material Technology Innovation Fund for National Defense Technology Industry, Science and Technology Department of Henan Province
Catalysis‑induced highly‑stable interface on porous silicon for high‑rate lithium‑ion batteries
Shanghai Jiao Tong University Journal CenterSilicon stands as a key anode material in lithium-ion battery ascribing to its high energy density. Nevertheless, the poor rate performance and limited cycling life remain unresolved through conventional approaches that involve carbon composites or nanostructures, primarily due to the un-controllable effects arising from the substantial formation of a solid electrolyte interphase (SEI) during the cycling. Here, an ultra-thin and homogeneous Ti doping alumina oxide catalytic interface is meticulously applied on the porous Si through a synergistic etching and hydrolysis process. This defect-rich oxide interface promotes a selective adsorption of fluoroethylene carbonate, leading to a catalytic reaction that can be aptly described as “molecular concentration-in situ conversion”. The resultant inorganic-rich SEI layer is electrochemical stable and favors ion-transport, particularly at high-rate cycling and high temperature. The robustly shielded porous Si, with a large surface area, achieves a high initial Coulombic efficiency of 84.7% and delivers exceptional high-rate performance at 25 A g−1 (692 mAh g−1) and a high Coulombic efficiency of 99.7% over 1000 cycles. The robust SEI constructed through a precious catalytic layer promises significant advantages for the fast development of silicon-based anode in fast-charging batteries.
- Journal
- Nano-Micro Letters
Cationic adsorption‑induced microlevelling effect: a pathway to dendrite‑free zinc anodes
Shanghai Jiao Tong University Journal CenterDendrite growth represents one of the most significant challenges that impede the development of aqueous zinc-ion batteries. Herein, Gd3+ ions are introduced into conventional electrolytes as a microlevelling agent to achieve dendrite-free zinc electrodeposition. Simulation and experimental results demonstrate that these Gd3+ ions are preferentially adsorbed onto the zinc surface, which enables dendrite-free zinc anodes by activating the microlevelling effect during electrodeposition. In addition, the Gd3+ additives effectively inhibit side reactions and facilitate the desolvation of [Zn(H2O)6]2+, leading to highly reversible zinc plating/stripping. Due to these improvements, the zinc anode demonstrates a significantly prolonged cycle life of 2100 h and achieves an exceptional average Coulombic efficiency of 99.72% over 1400 cycles. More importantly, the Zn//NH4V4O10 full cell shows a high capacity retention rate of 85.6% after 1000 cycles. This work not only broadens the application of metallic cations in battery electrolytes but also provides fundamental insights into their working mechanisms.
- Journal
- Nano-Micro Letters
Tunable platform capacity of metal–organic frameworks via high‑entropy strategy for ultra‑fast sodium storage
Shanghai Jiao Tong University Journal CenterPrecise regulation of the platform capacity/voltage of electrode materials contributes to the efficient operation of sodium-ion fast-charging devices. However, the design of such electrode materials is still in a blank stage. Herein, based on tunable metal–organic frameworks, we have designed a novel material system—two-dimensional high-entropy metal–organic frameworks (HE-MOFs), which exhibits unique properties in sodium storage and is of vital importance for realizing fast-charging batteries. Furthermore, we have found that the high-entropy effect can regulate the electronic structure, the sodium-ion migration environment, and the sodium-ion storage active sites, thereby meeting the requirements of electrode materials for sodium-ion fast-charging devices. Impressively, the HE-MOFs material still maintains a reversible specific capacity of 89 mAh g−1 at a current density of 20 A g−1. It presents an ideal sodium storage voltage plateau of approximately 0.5 V, and its platform capacity is increased to 122.7 mAh g−1, far superior to that of Mn-MOFs (with no platform capacity). This helps to reduce safety hazards during the fast-charging process and demonstrates its great application value in the fields of fast-charging sodium-ion batteries and capacitors. Our research findings have broken the barriers to the application of non-conductive MOFs as energy storage materials, enhanced the understanding of the regulation of platform capacity and voltage, and paved the way for the realization of high-security sodium-ion fast-charging devices.
- Journal
- Nano-Micro Letters
Toward massive satellite signals of opportunity positioning: Challenges, methods, and experiments
Beijing Institute of Technology Press Co., LtdGust response alleviation via wingtip bending freely with fluid-structure interaction approach based on dynamic modal rotation method
SciOpenGust load alleviation is a crucial topic for the practical application of high-altitude long-endurance unmanned aerial vehicles. Passive flexible wingtips mitigate gust loads by naturally adapting their shape to airflow disturbances. Without active control or energy input, they passively relieve aerodynamic peaks, smooth transient loads, and enhance flight stability and structural safety, offering a lightweight, reliable, and energy-efficient gust alleviation solution.
- Journal
- Chinese Journal of Aeronautics
Escherichia albertii: The still unfolding journey of a misdiagnosed pathogen
Osaka Metropolitan University- Journal
- Microbiology and Molecular Biology Reviews
Potassium supercharges biochar for cleaner air by unlocking molecular pathways to trap toxic nitrogen dioxide
Biochar Editorial Office, Shenyang Agricultural University- Journal
- Biochar
Defect engineering in two-dimensional materials for photocatalysis: A mini-review of first-principles design
Shanghai Jiao Tong University Journal Center- Journal
- Frontiers in Energy