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Updates every hour. Last Updated: 27-Oct-2026 23:17 ET (28-Oct-2026 03:17 GMT/UTC)
Green dithioester synthesis reaction developed for a brighter tomorrow
Tsinghua University PressCurrent dithioester synthesis methods are cumbersome, inefficient and often toxic. A research team recently developed a green synthesis technique for dithioester generation using sulfide powder, alkyl bromides and aromatic aldehydes as precursor molecules in a photocatalysis reaction.
- Journal
- Polyoxometalates
Progress and development trend of space backlight detection imaging technology
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Mars crater production function based on mapped crater populations
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Solar sail transfers under uncertainties: A deep reinforcement learning approach
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Attitude-orbit coordinated control of spacecraft formation for heliocentric gravitational-wave detection with large-scale communication delays
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Application of symmetrical motorized momentum exchange tethers for two-way Earth–Mars transportation
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Real-time remote sensing for sudden surface anomalies: a review of principles and challenges
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Ligand-controlled tunable distal C(sp2)–H functionalization of aryl and benzyl phosphonates
Shanghai Jiao Tong University Journal CenterAchieving regioselective C–H functionalization is a particularly difficult issue in organic chemistry when these C–H bonds have similar reactivity. Although significant progress has been made in regioselective C–H functionalization at one specific site, the tunable version of such processes is rarely documented. Here we describe a tunable meta- and para-selective C–H borylation of aryl and benzyl phosphonates, in which the regioselectivity can be switched by bifunctional ligands. A broad range of substrates are compatible and exhibit good to excellent regioselectivity under mild reaction conditions. Benzyl phosphonates can be conveniently transformed into styrene derivatives via Horner–Wadsworth–Emmons olefination. Gram-scale preparation and derivatization of borylated products demonstrate the important application of our method in synthetic chemistry. The orthogonality of two functional Bpin and phosphorylmethyl groups provides ample opportunity for increasing the diversity of styrene derivatives with precise site-control.
Modulating in-plane conjugation and core polarity in naphthalimide-based covalent organic frameworks enables efficient H2O2 photosynthesis
Shanghai Jiao Tong University Journal CenterEfficient photocatalytic H2O2 production is a sustainable alternative to the anthraquinone process, yet designing photocatalysts with both high activity and selectivity is extremely challenging. Covalent organic frameworks (COFs) offer modular architectures and tunable electronic structures, but precise electronic modulation for maximizing H2O2 photosynthesis is rarely attained. Here we report a series of naphthalimide-based donor–acceptor COFs with systematically engineered cores. Among them, NDI–B–COF (benzene core) delivers an outstanding H2O2 yield of 11,025 μmol g−1 h−1 (with sacrificial agent), far surpassing its nitrogen- and triazine-core analogs. This performance stems from synergistic effects of an extended in-plane conjugation and a reduced core polarity, which collectively enhance charge separation, directional carrier transport, and *OH intermediate formation, thereby lowering the barrier for two-electron water oxidation. These findings establish a clear structure–property–activity correlation and offer a general strategy for developing highly efficient metal-free photocatalysts.