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Updates every hour. Last Updated: 28-Oct-2026 11:16 ET (28-Oct-2026 15:16 GMT/UTC)
Real-time remote sensing for sudden surface anomalies: a review of principles and challenges
Beijing Institute of Technology Press Co., Ltd- Journal
- Space: Science & Technology
Ligand-controlled tunable distal C(sp2)–H functionalization of aryl and benzyl phosphonates
Shanghai Jiao Tong University Journal CenterAchieving regioselective C–H functionalization is a particularly difficult issue in organic chemistry when these C–H bonds have similar reactivity. Although significant progress has been made in regioselective C–H functionalization at one specific site, the tunable version of such processes is rarely documented. Here we describe a tunable meta- and para-selective C–H borylation of aryl and benzyl phosphonates, in which the regioselectivity can be switched by bifunctional ligands. A broad range of substrates are compatible and exhibit good to excellent regioselectivity under mild reaction conditions. Benzyl phosphonates can be conveniently transformed into styrene derivatives via Horner–Wadsworth–Emmons olefination. Gram-scale preparation and derivatization of borylated products demonstrate the important application of our method in synthetic chemistry. The orthogonality of two functional Bpin and phosphorylmethyl groups provides ample opportunity for increasing the diversity of styrene derivatives with precise site-control.
Modulating in-plane conjugation and core polarity in naphthalimide-based covalent organic frameworks enables efficient H2O2 photosynthesis
Shanghai Jiao Tong University Journal CenterEfficient photocatalytic H2O2 production is a sustainable alternative to the anthraquinone process, yet designing photocatalysts with both high activity and selectivity is extremely challenging. Covalent organic frameworks (COFs) offer modular architectures and tunable electronic structures, but precise electronic modulation for maximizing H2O2 photosynthesis is rarely attained. Here we report a series of naphthalimide-based donor–acceptor COFs with systematically engineered cores. Among them, NDI–B–COF (benzene core) delivers an outstanding H2O2 yield of 11,025 μmol g−1 h−1 (with sacrificial agent), far surpassing its nitrogen- and triazine-core analogs. This performance stems from synergistic effects of an extended in-plane conjugation and a reduced core polarity, which collectively enhance charge separation, directional carrier transport, and *OH intermediate formation, thereby lowering the barrier for two-electron water oxidation. These findings establish a clear structure–property–activity correlation and offer a general strategy for developing highly efficient metal-free photocatalysts.
Brain and heart responses to real vs. artificial flowers in elderly women
Osaka Metropolitan University- Journal
- HortScience
Older teens entering care often overlooked
Griffith UniversityThere is an urgent need for better support for older teenagers entering care for the first time, new Griffith University research has found.
- Journal
- Child and Adolescent Social Work Journal
Drug-resistant gonorrhea: Why it matters and what comes next
University of California - Los Angeles Health SciencesDrug-resistant Neisseria gonorrhoeae (the bacterium that causes gonorrhea) has become one of the most urgent antimicrobial resistant threats to public health worldwide. As gonorrhea rates rise and treatment options become more limited, researchers are calling for a more tailored approach that combines new diagnostics, rapid resistance testing, surveillance and additional treatment options for the sexually transmitted disease.
- Journal
- Clinical Infectious Diseases
Dual-design carbon catalyst helps lithium–oxygen batteries deliver high capacity with lower energy loss
Shenyang Agricultural University Collaborative Journals- Journal
- Sustainable Carbon Materials
SFU chemists supercharge antiviral drug discovery
Simon Fraser University- Journal
- Science
JMIR Aging Study finds digital mindfulness app delivers rapid stress relief for dementia caregivers within 3 weeks
JMIR Publications- Journal
- JMIR Aging