Multi-resonance emitters with phosphorus-bridged cyclization: Spectral narrowing synergized with accelerated reverse intersystem crossing
Peer-Reviewed Publication
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Duan and co-workers developed a phosphorus-carbon-bridged cyclization strategy for MR-TADF emitters, addressing the challenge of balancing narrowband emission and efficient RISC. It rigidifies skeletons to suppress high-frequency vibrations and leverages P/S heavy-atom effects to enhance spin-orbital coupling. Two blue emitters, BCzBN-PO (467 nm, 19 nm FWHM) and BCzBN-PS (474 nm, 18 nm FWHM), were synthesized. BCzBN-PS achieved a kRISC of 8.5×105 s−1 (8-fold higher than BCzBN-PO). Non-sensitized OLEDs showed FWHM < 30 nm and EQE > 20%, while TADF-sensitized devices exhibited higher EQE (43.0% vs. 41.2%) and lower roll-off (25.9% vs. 30.1% at 1000 cd m−2) for BCzBN-PS. This work establishes a paradigm balancing color purity and exciton utilization, advancing narrowband electroluminescence.
A research team led by Professor Lu Jian, Dean of the College of Engineering and Chair Professor in the Department of Mechanical Engineering at City University of Hong Kong, has discovered for the first time that the naturally occurring porous ceramic structure within sea urchin spines possesses an unexpected capability for mechanoelectrical perception.
In a recent study published in Science China Earth Sciences, a team of researchers proposed using an orthogonal conditional nonlinear optimal perturbations (O-CNOPs) method to tackle the challenge of forecasting unusual tropical cyclone (TC) tracks. Their findings revealed that this method exhibits exceptional capability in generating ensemble members that accurately predict sharp TC turns. The O-CNOPs method holds potential as a transformative tool for addressing the forecasting challenge, offering a more precise and reliable solution for predicting TC behavior.
Forecasting unusual TC tracks has long been a persistent challenge in TC prediction, with limited progress made over the years. However, this study demonstrated that the O-CNOPs outperformed traditional methods [singular vectors (SVs) and bred vectors (BVs)] by providing more stable and reliable improvements in TC track forecasting skills. Notably, at lead times of one to five days, the O-CNOPs showed superior ability to generate ensemble members that accurately predict sharp TC turns. Thus, the study offers a new ensemble forecasting technology to enhance the accuracy of unusual TC track forecasts, with potential for becoming a valuable approach to address this forecasting challenge.
Bird migration is awe-inspiring. Animals mostly made of feathers take to the sky and complete round-trip journeys up to 40,000 kilometers long. The extremists migrate nonstop. Some fast the entire way. Most migratory species, however, engage in what ornithologists refer to as “stopovers” to refuel, rest, and wait out storms. A new literature review published in the Journal of Raptor Research emphasizes the need for more investigation into the importance of these stopover sites, newly defined in the review as places where individuals “pause their migratory movements for at least twenty-four hours.” Raptors are top predators with far-reaching impacts on their surrounding habitat, and they respond quickly to environmental change, making them effective bioindicators. Bolstering our knowledge of which areas are most crucial to the success of these long-distance journeys is therefore necessary, and increasingly possible as tracking technology improves.
Researchers from the Center of Excellence in Marine Biotechnology at Sultan Qaboos University (SQU), in collaboration with Macro Algae Industries, have launched a pilot seaweed farm near the Al Sawadi Islands in Barka to evaluate the commercial feasibility of cultivating native seaweed species in Omani waters.
A study published in The Journal of Engineering Research (TJER) at Sultan Qaboos University presents an advanced intrusion detection system (IDS) designed to improve the accuracy and efficiency of identifying cyber-attacks. The proposed model combines a double feature selection technique with a stacked ensemble machine learning approach to enhance detection performance while reducing computational complexity.
Thermally integrated Carnot battery (TI-CB) systems offer unique advantages for industrial waste heat recovery, but their performance under fluctuating, off-design conditions remains poorly understood. To address this gap, this study proposes a quasi-dynamic mathematical model with solution methodologies applicable to both design and off-design operating conditions. A dynamic evaluation framework is also developed to account for the temporal mismatch between energy storage and release processes. A multi-operating-condition set constructed via multivariable sampling is used to enable systematic analysis of key design parameters under both design and off-design conditions. The results reveal that heat source utilization parameters and heat pump temperature rise are dominant factors affecting TI-CB performance, while off-design analysis shows that ORC mass flow rate variations have a more significant impact on system performance than heat pump fluctuations. Due to irreversible heat losses, an increase in the heat source temperature difference leads to a decrease in round-trip efficiency (ηrt) from 62.6% to 45.8%, while ηorc and ηex also exhibit downward trends. A higher temperature lift in the heat pump results a decrease in the mean COP from 7.6 to 4.8, whereas ηorc increases from 7.0% to 10.2%. Among working fluids evaluated, R1336mzz(Z) demonstrates superior performance but exhibits nonlinear behavior, while R1233zd(E) provides optimal stability across operating ranges, making it suitable for practical engineering applications.